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Structure and catalytic activity of a hexarhenium cluster-supported copper cubanes [{Cu4(μ-OH)4(NH3)7}2{Re6Se8(CN)6}][Re6Se8(CN)6] · 2H2O

Title
Structure and catalytic activity of a hexarhenium cluster-supported copper cubanes [{Cu4(μ-OH)4(NH3)7}2{Re6Se8(CN)6}][Re6Se8(CN)6] · 2H2O
Authors
Xu L.Kim Y.Kim S.-J.Kim H.J.Kim C.
Ewha Authors
김성진김영미
SCOPUS Author ID
김성진scopus; 김영미scopus
Issue Date
2007
Journal Title
Inorganic Chemistry Communications
ISSN
1387-7003JCR Link
Citation
vol. 10, no. 5, pp. 586 - 589
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
The first hexarhenium cluster-supported Cu4(OH)4 cubanes had been synthesized. The complex displayed a belt-like one-dimensional structure with dangling Cu4 cubanes. As a heterogeneous catalyst, the complex showed a high catalytic activity in the transesterification of a range of esters with methanol under the mild conditions. Moreover, it can be reused without any loss of activity through five runs with ester, which suggests that this catalyst is an efficient, mild, and easily recyclable one for the alcoholysis of esters. © 2007 Elsevier B.V. All rights reserved.
DOI
10.1016/j.inoche.2007.02.005
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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