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Experimental and theoretical evidence for nonheme iron(III) alkylperoxo species as sluggish oxidants in oxygenation reactions

Title
Experimental and theoretical evidence for nonheme iron(III) alkylperoxo species as sluggish oxidants in oxygenation reactions
Authors
Seo M.S.Kamachi T.Kouno T.Murata K.Park M.J.Yoshizawa K.Nam W.
Ewha Authors
남원우서미숙
SCOPUS Author ID
남원우scopus
Issue Date
2007
Journal Title
Angewandte Chemie - International Edition
ISSN
1433-7851JCR Link
Citation
vol. 46, no. 13, pp. 2291 - 2294
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
The active oxidant that oxygenates organic substrates is an iron(IV) oxo intermediate, namely, [(tpa)FeIV(O)(CH3CN)]2+ (2), which is formed through O-O bond homolysis, according to experimental and computational studies on the reactivity of nonheme iron(III) alkylperoxo complex [(tpa)FeIII(OOtBu)(CH3CN)]2+ (1), which was shown to be a sluggish electrophilic oxidant that is incapable of oxygenating organic substrates. tpa = tris(2-pyridylmethyl)amine. (Chemical Equation Presented). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
DOI
10.1002/anie.200604219
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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