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Bioinspired chemical inversion of L-amino acids to D-amino acids

Title
Bioinspired chemical inversion of L-amino acids to D-amino acids
Authors
Park H.Kwan M.K.Lee A.Ham S.Nam W.Chin J.
Ewha Authors
남원우김관묵
SCOPUS Author ID
남원우scopus; 김관묵scopus
Issue Date
2007
Journal Title
Journal of the American Chemical Society
ISSN
0002-7863JCR Link
Citation
vol. 129, no. 6, pp. 1518 - 1519
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
An organic receptor (1) that binds a wide variety of amino acids with the same sense of stereoselectivity (d/l ratio of about 10) has been developed. This receptor binds amino acids by formation of imines with internal resonance-assisted hydrogen bonds much as in imines formed between pyridoxal and amino acids. The internal resonance-assisted hydrogen bond is used to activate the bound amino acids and convert l-amino acids to d-amino acids. Copyright © 2007 American Chemical Society.
DOI
10.1021/ja067724g
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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