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dc.contributor.author남원우-
dc.contributor.author김진흥-
dc.contributor.author서미숙-
dc.date.accessioned2017-02-15T08:02:49Z-
dc.date.available2017-02-15T08:02:49Z-
dc.date.issued2007-
dc.identifier.issn0020-1669-
dc.identifier.otherOAK-3735-
dc.identifier.urihttp://dspace.ewha.ac.kr/handle/2015.oak/234199-
dc.description.abstractNonheme and heme iron monooxygenases participate in oxidative N-dealkylation reactions in nature, and high-valent oxoiron(IV) species have been invoked as active oxidants that effect the oxygenation of organic substrates. The present study describes the first example of the oxidative N-dealkylation of N,N-dialkylamines by synthetic nonheme oxoiron(IV) complexes and the reactivity comparisons of nonheme and heme oxoiron(IV) complexes. Detailed mechanistic studies were performed with various N,N-dialkylaniline substrates such as para-substituted N,N-dimethylanilines, para-chloro-N-ethyl-N- methylaniline, para-chloro-N-cyclopropyl-N-isopropylaniline, and deuteriated N,N-dimethylanilines. The results of a linear free-energy correlation, inter- and intramolecular kinetic isotope effects, and product analysis studied with the mechanistic probes demonstrate that the oxidative N-dealkylation reactions by nonheme and heme oxoiron(IV) complexes occur via an electron transfer-proton transfer (ET-PT) mechanism. © 2007 American Chemical Society.-
dc.languageEnglish-
dc.titleOxidative N-dealkylation reactions by oxoiron(IV) complexes of nonheme and heme ligands-
dc.typeArticle-
dc.relation.issue1-
dc.relation.volume46-
dc.relation.indexSCI-
dc.relation.indexSCIE-
dc.relation.indexSCOPUS-
dc.relation.startpage293-
dc.relation.lastpage298-
dc.relation.journaltitleInorganic Chemistry-
dc.identifier.doi10.1021/ic0614014-
dc.identifier.wosidWOS:000243157100036-
dc.identifier.scopusid2-s2.0-33846403701-
dc.author.googleNehru K.-
dc.author.googleSeo M.S.-
dc.author.googleKim J.-
dc.author.googleNam W.-
dc.contributor.scopusid남원우(7006569723)-
dc.contributor.scopusid김진흥(8580015800)-
dc.date.modifydate20170601134213-
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자연과학대학 > 화학·나노과학전공 > Journal papers
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