Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 남원우 | * |
dc.contributor.author | Shunichi Fukuzumi | * |
dc.contributor.author | 이용민 | * |
dc.date.accessioned | 2016-12-27T02:12:42Z | - |
dc.date.available | 2016-12-27T02:12:42Z | - |
dc.date.issued | 2017 | * |
dc.identifier.issn | 0010-8545 | * |
dc.identifier.other | OAK-19843 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/233227 | - |
dc.description.abstract | High-valent metal-oxo complexes are produced by successive electron-transfer oxidation of metal complexes with one-electron oxidants in the presence of water, which is an oxygen source in the generation of the metal-oxo complexes. Then, metal-oxo complexes oxidize substrates to yield oxygenated substrates, accompanied by the regeneration of reduced metal complexes. Thus, the oxidation of substrates using one-electron oxidants can be catalyzed by metal complexes via formation of high-valent metal-oxo complexes by the electron-transfer oxidation of metal complexes in the presence of water as an oxygen source. When water is used as a substrate, water is oxidized by one-electron oxidants to evolve dioxygen via an O[sbnd]O bond formation process. The one-electron oxidants used for the formation of high-valent metal-oxo complexes can be replaced by much weaker oxidants, when a photosensitizing metal complex, such as [Ru(bpy)3]2+ (bpy = 2,2′-bipyridine), is employed as a photocatalyst, an oxidized form of the photocatalyst, which is generated via photoinduced electron transfer from the excited state to a weaker oxidant, can oxidize metal complexes in the presence of water to afford the high-valent metal-oxo complexes. Thus, the oxidation of substrates, including water oxidation, by weak oxidants can be catalyzed by metal complexes under photoirradiation of the photocatalyst using water as an oxygen source. © 2016 Elsevier B.V. | * |
dc.language | English | * |
dc.publisher | Elsevier B.V. | * |
dc.subject | Electron transfer | * |
dc.subject | High-valent metal-oxo complexes | * |
dc.subject | Photocatalyst | * |
dc.subject | Photoinduced electron transfer | * |
dc.subject | Redox catalysis | * |
dc.title | High-valent metal-oxo complexes generated in catalytic oxidation reactions using water as an oxygen source | * |
dc.type | Review | * |
dc.relation.volume | 333 | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 44 | * |
dc.relation.lastpage | 56 | * |
dc.relation.journaltitle | Coordination Chemistry Reviews | * |
dc.identifier.doi | 10.1016/j.ccr.2016.09.018 | * |
dc.identifier.wosid | WOS:000392771000003 | * |
dc.identifier.scopusid | 2-s2.0-84997839916 | * |
dc.author.google | Fukuzumi S. | * |
dc.author.google | Kojima T. | * |
dc.author.google | Lee Y.-M. | * |
dc.author.google | Nam W. | * |
dc.contributor.scopusid | 남원우(7006569723) | * |
dc.contributor.scopusid | Shunichi Fukuzumi(35430038100;58409757400) | * |
dc.contributor.scopusid | 이용민(36546331100;35233855500;57192113229) | * |
dc.date.modifydate | 20240401081001 | * |