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Reactive extraction of enantiomers of 1,2-amino alcohols via stereoselective thermodynamic and kinetic processes

Title
Reactive extraction of enantiomers of 1,2-amino alcohols via stereoselective thermodynamic and kinetic processes
Authors
Tang L.Choi S.Nandhakumar R.Park F.Chung H.Chin J.Kwan M.K.
Ewha Authors
김관묵
SCOPUS Author ID
김관묵scopus
Issue Date
2008
Journal Title
Journal of Organic Chemistry
ISSN
0022-3263JCR Link
Citation
vol. 73, no. 15, pp. 5996 - 5999
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
(Chemical Equation Presented) (R)-Amino alcohol with an enantiomeric excess of >95% was resolved by reactive extraction processes from 2 equiv of racemic alcohol using a chiral receptor 2 as an enantioselective extractant. One resolution cycle is composed of three extractions: a stereoselective reversible imine formation, a stereoselective irreversible imine hydrolysis, and the recovery of 2 and enantiomeric amino alcohols. © 2008 American Chemical Society.
DOI
10.1021/jo800670t
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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