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A mononuclear nonheme cobalt(III)-hydroperoxide complex with an amphoteric reactivity in electrophilic and nucleophilic oxidative reactions

Title
A mononuclear nonheme cobalt(III)-hydroperoxide complex with an amphoteric reactivity in electrophilic and nucleophilic oxidative reactions
Authors
Tcho, Woon-YoungWang, BinLee, Yong-MinCho, Kyung-BinShearer, JasonNam, Wonwoo
Ewha Authors
남원우이용민
SCOPUS Author ID
남원우scopus; 이용민scopusscopusscopus
Issue Date
2016
Journal Title
DALTON TRANSACTIONS
ISSN
1477-9226JCR Link

1477-9234JCR Link
Citation
DALTON TRANSACTIONS vol. 45, no. 37, pp. 14511 - 14515
Publisher
ROYAL SOC CHEMISTRY
Indexed
SCIE; SCOPUS WOS scopus
Document Type
Article
Abstract
A mononuclear nonheme cobalt(III)-hydroperoxide complex bearing a tetramethylated cyclam ligand, [(12-TMC)Co-III(OOH)](2+), was synthesized and characterized spectroscopically and computationally; the cobalt(III)-hydroperoxide complex exhibited an amphoteric reactivity in electrophilic and nucleophilic oxidative reactions.
DOI
10.1039/c6dt01194b
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자연과학대학 > 화학·나노과학전공 > Journal papers
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