Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 남원우 | * |
dc.date.accessioned | 2016-11-15T02:11:35Z | - |
dc.date.available | 2016-11-15T02:11:35Z | - |
dc.date.issued | 2016 | * |
dc.identifier.issn | 1477-9226 | * |
dc.identifier.issn | 1477-9234 | * |
dc.identifier.other | OAK-19443 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/232677 | - |
dc.description.abstract | In addition to oxometal [Mn+=O] and imidometal [Mn+=NR] units, transient metal-iodosylarene [M(n- 2)+-O=IPh] and metal-iminoiodane [M(n- 2)+-N(R)=IPh] adducts are often invoked as a possible "second oxidant" responsible for the oxo and imido group transfer reactivity. Although a few metal-iodosylarene adducts have been recently isolated and/or spectroscopically characterized, metal-iminoiodane adducts have remained elusive. Herein, we provide UV-Vis, EPR, NMR, XAS and DFT evidence supporting the formation of a metal-iminoiodane complex 2 and its scandium adduct 2-Sc. 2 and 2-Sc are reactive toward substrates in the hydrogen-atom and nitrene transfer reactions, which confirm their potential as active oxidants in metal-catalyzed oxidative transformations. Oxidation of para-substituted 2,6-di-tert-butylphenols by 2 and 2-Sc can occur by both coupled and uncoupled proton and electron transfer mechanisms; the exact mechanism depends on the nature of the para substituent. | * |
dc.language | English | * |
dc.publisher | ROYAL SOC CHEMISTRY | * |
dc.title | A cobalt(II) iminoiodane complex and its scandium adduct: mechanistic promiscuity in hydrogen atom abstraction reactions | * |
dc.type | Article | * |
dc.relation.issue | 37 | * |
dc.relation.volume | 45 | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 14538 | * |
dc.relation.lastpage | 14543 | * |
dc.relation.journaltitle | DALTON TRANSACTIONS | * |
dc.identifier.doi | 10.1039/c6dt01815g | * |
dc.identifier.wosid | WOS:000384404700012 | * |
dc.identifier.scopusid | 2-s2.0-84988592578 | * |
dc.author.google | Kundu, Subrata | * |
dc.author.google | Chernev, Petko | * |
dc.author.google | Engelmann, Xenia | * |
dc.author.google | Chung, Chan Siu | * |
dc.author.google | Dau, Holger | * |
dc.author.google | Bill, Eckhard | * |
dc.author.google | England, Jason | * |
dc.author.google | Nam, Wonwoo | * |
dc.author.google | Ray, Kallol | * |
dc.contributor.scopusid | 남원우(7006569723) | * |
dc.date.modifydate | 20240116111857 | * |