View : 11 Download: 0

The first octahedral cluster complexes with terminal formate ligands: Synthesis, structure, and properties of K4[Re6S 8(HCOO)6] and Cs4[Re6S 8(HCOO)6]

Title
The first octahedral cluster complexes with terminal formate ligands: Synthesis, structure, and properties of K4[Re6S 8(HCOO)6] and Cs4[Re6S 8(HCOO)6]
Authors
Brylev K.A.Mironov Y.V.Kozlova S.G.Fedorov V.E.Kim S.-J.Pietzsch H.-J.Stephan H.Ito A.Ishizaka S.Kitamura N.
Ewha Authors
김성진
SCOPUS Author ID
김성진scopus
Issue Date
2009
Journal Title
Inorganic Chemistry
ISSN
0020-1669JCR Link
Citation
vol. 48, no. 5, pp. 2309 - 2315
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
The hexarhenium anionic cluster complex with terminal formate ligands [Re6S8(HCOO)6]4- was obtained by the room-temperature reaction between [Re6S8(OH) 6]4- and formic acid in an aqueous solution. The cluster was crystallized as a potassium or cesium salt and characterized by X-ray single-crystal diffraction and elemental analyses, IR, 1H NMR, UV/vis, and luminescence spectroscopies. In particular, the emission quantum yield of the potassium salt of the Re6 cluster anion in the solid phase was determined for the first time. The electronic structures of [Re 6S8(HCOO)6]4- and [Re 6S8(OH)6]4- were also elucidated by DFT calculations. © 2009 American Chemical Socity.
DOI
10.1021/ic802178q
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
Files in This Item:
There are no files associated with this item.
Export
RIS (EndNote)
XLS (Excel)
XML


qrcode

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

BROWSE