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dc.contributor.author남원우-
dc.contributor.author이용민-
dc.date.accessioned2016-09-21T01:09:15Z-
dc.date.available2016-09-21T01:09:15Z-
dc.date.issued2016-
dc.identifier.issn1433-7851-
dc.identifier.issn1521-3773-
dc.identifier.otherOAK-19294-
dc.identifier.urihttp://dspace.ewha.ac.kr/handle/2015.oak/232248-
dc.description.abstractReactions of nonheme Fe-III-superoxo and Mn-IV-peroxo complexes bearing a common tetraamido macrocyclic ligand (TAML), namely [(TAML)Fe-III(O-2)](2-) and [(TAML)Mn-IV(O-2)](2-), with nitric oxide (NO) afford the Fe-III-NO3 complex [(TAML)Fe-III(NO3)](2-) and the Mn-V-oxo complex [(TAML)Mn-V(O)](-) plus NO2-, respectively. Mechanistic studies, including density functional theory (DFT) calculations, reveal that M-III-peroxynitrite (M=Fe and Mn) species, generated in the reactions of [(TAML)Fe-III(O-2)](2-) and [(TAML)Mn-IV(O-2)](2-) with NO, are converted into M-IV(O) and CNO2 species through O-O bond homolysis of the peroxynitrite ligand. Then, a rebound of Fe-IV(O) with CNO2 affords [(TAML)Fe-III(NO3)](2-), whereas electron transfer from Mn-IV(O) to CNO2 yields [(TAML)Mn-V(O)](-) plus NO2-.-
dc.languageEnglish-
dc.publisherWILEY-V C H VERLAG GMBH-
dc.subjectbiomimetic chemistry-
dc.subjectiron-
dc.subjectmanganese-
dc.subjectnonheme metal-oxo complexes-
dc.subjectreactive nitrogen species-
dc.titleMechanistic Insight into the Nitric Oxide Dioxygenation Reaction of Nonheme Iron(III)-Superoxo and Manganese(IV)-Peroxo Complexes-
dc.typeArticle-
dc.relation.issue40-
dc.relation.volume55-
dc.relation.indexSCIE-
dc.relation.indexSCOPUS-
dc.relation.startpage12403-
dc.relation.lastpage12407-
dc.relation.journaltitleANGEWANDTE CHEMIE-INTERNATIONAL EDITION-
dc.identifier.doi10.1002/anie.201605705-
dc.identifier.wosidWOS:000384713700047-
dc.identifier.scopusid2-s2.0-84984908111-
dc.author.googleHong, Seungwoo-
dc.author.googleKumar, Pankaj-
dc.author.googleCho, Kyung-Bin-
dc.author.googleLee, Yong-Min-
dc.author.googleKarlin, Kenneth D.-
dc.author.googleNam, Wonwoo-
dc.contributor.scopusid남원우(7006569723)-
dc.contributor.scopusid이용민(36546331100;35233855500)-
dc.date.modifydate20180104081001-
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자연과학대학 > 화학·나노과학전공 > Journal papers
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