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Tandem blaise-alkenylation with unactivated alkynes: One-pot synthesis of α-vinylated β-enaminoesters from nitriles

Title
Tandem blaise-alkenylation with unactivated alkynes: One-pot synthesis of α-vinylated β-enaminoesters from nitriles
Authors
Chun Y.S.Ko Y.O.Shin H.Lee S.-G.
Ewha Authors
이상기전유성
SCOPUS Author ID
이상기scopus
Issue Date
2009
Journal Title
Organic Letters
ISSN
1523-7060JCR Link
Citation
vol. 11, no. 15, pp. 3414 - 3417
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
The in situ generated Blaise reaction intermediate, a zinc bromide complex of β-enaminoester, reacts with various unactivated terminal alkynes and an internal alkyne under mild conditions to afford α-vinylated β-enaminoesters in good to excellent yields. © 2009 American Chemical Society.
DOI
10.1021/ol901241s
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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