View : 16 Download: 0

Multifunctional nickel-bisdithiolate complexes with trans-4-[2-(1- ferrocenyl)Vinyl]-1-methylpyridinium cation

Title
Multifunctional nickel-bisdithiolate complexes with trans-4-[2-(1- ferrocenyl)Vinyl]-1-methylpyridinium cation
Authors
Noh D.-Y.Lee H.-J.Kang H.Kang W.Lee U.
Ewha Authors
강원
SCOPUS Author ID
강원scopus
Issue Date
2002
Journal Title
Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
ISSN
1058-725XJCR Link
Citation
vol. 376, pp. 269 - 274
Indexed
SCOPUS WOS scopus
Abstract
Nickel-bisdithiolate complexes with a ferrocene-containing 2nd order nonlinear optical chromophore as a cation, (FcCH=CHPyMe)[NiL2] where L = dmit (1a), dddt (1b) and debt (1c) were synthesized by the cation exchange reaction. In the X-ray crystal structure of complex (1a), no intrastack but interstack S...S interactions less than 3.7 Å are observed. This complex was revealed to be an insulator at room temperature. However, (FcCH=CHPyMe) x[Ni(dmit)2] (0 < x < 1) (3) needle grown in an H-type electrochemical cell shows semiconductor behavior (Ea =106 meV) over the temperature range measured (30 ∼300 K) with σRT = 1 Ω-1cm-1. The electronic transition at UV-vis-NIR region was measured for the nickel complexes and discussed.
DOI
10.1080/10587250210737
Appears in Collections:
자연과학대학 > 물리학전공 > Journal papers
Files in This Item:
There are no files associated with this item.
Export
RIS (EndNote)
XLS (Excel)
XML


qrcode

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

BROWSE