Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 김성진 | * |
dc.contributor.author | 김영미 | * |
dc.date.accessioned | 2016-08-28T11:08:52Z | - |
dc.date.available | 2016-08-28T11:08:52Z | - |
dc.date.issued | 2008 | * |
dc.identifier.issn | 1434-1948 | * |
dc.identifier.other | OAK-13142 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/229174 | - |
dc.description.abstract | We synthesized new mesostructured materials through the surfactant-templated assembly of octahedral rhenium cluster [Re 6Q8(CN)6]4- (Q = Te, Se and S) anions. The mesostructured lamellar phases with the general formula [C nH2n+1N-(CH3)3]4[Re 6Q8(CN)6] (n = 14, 16, 18; Q = Te, Se, S; 1: n = 14, Q = Te; 2: n = 16, Q = Te; 3: n = 18, Q = Te; 4: n = 16, Q = Se; 5: n = 16, Q = S) were prepared by an ion exchange/precipitation reaction of alkyltrimethylammonium surfactants and the corresponding cluster K 4[Re6Q8(CN)6] in an H 2O/acetone medium at room temperature. The orange plate-like crystals of 1 and 4 were obtained by slow concentration of their solutions and their crystal structures determined by single-crystal X-ray diffraction. In the structure, the rhenium clusters form layers with a pseudo-hexagonal arrangement, and these inorganic layers are separated by a bilayer of interdigitated surfactant cations. Compounds 1-5 were characterized using powder X-ray diffraction, TEM, IR, Raman, FL, UV/Vis spectroscopy, and thermogravimetric analysis. © Wiley-VCH Verlag GmbH & Co. KGaA, 2008. | * |
dc.language | English | * |
dc.title | Mesolamellar phases containing [Re6Q8(CN) 6]4- (Q = Te, Se, S) cluster anions | * |
dc.type | Article | * |
dc.relation.issue | 5 | * |
dc.relation.index | SCI | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 686 | * |
dc.relation.lastpage | 692 | * |
dc.relation.journaltitle | European Journal of Inorganic Chemistry | * |
dc.identifier.doi | 10.1002/ejic.200701125 | * |
dc.identifier.wosid | WOS:000254593800004 | * |
dc.identifier.scopusid | 2-s2.0-53349178165 | * |
dc.author.google | Suh M.-J. | * |
dc.author.google | Vien V. | * |
dc.author.google | Huh S. | * |
dc.author.google | Kim Y. | * |
dc.author.google | Kim S.-J. | * |
dc.contributor.scopusid | 김성진(56812714700) | * |
dc.contributor.scopusid | 김영미(57207443602) | * |
dc.date.modifydate | 20240301081003 | * |