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The effect of solvent on the α-effect: Abnormal nucleophilic reactivity of substituted acetophenone oximate anions in aqueous DMSO

Title
The effect of solvent on the α-effect: Abnormal nucleophilic reactivity of substituted acetophenone oximate anions in aqueous DMSO
Authors
Ik-Hwan U.Su-Jin O.Dong-Sook K.
Ewha Authors
권동숙엄익환
SCOPUS Author ID
권동숙scopusscopus; 엄익환scopusscopus
Issue Date
1995
Journal Title
Tetrahedron Letters
ISSN
0040-4039JCR Link
Citation
vol. 36, no. 38, pp. 6903 - 6906
Indexed
SCI; SCIE; SCOPUS scopus
Abstract
The nucleophilic reactivity of substituted acetophenone oximate anions decreases with increasing base strengthening ability of the substituent, resulting in a positive Hammett ρ value in H 2O containing 20 mole % DMSO.
DOI
10.1016/00404-0399(50)1426I-
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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