Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 이상기 | * |
dc.contributor.author | 김주현 | * |
dc.date.accessioned | 2016-08-28T10:08:10Z | - |
dc.date.available | 2016-08-28T10:08:10Z | - |
dc.date.issued | 2013 | * |
dc.identifier.issn | 1523-7060 | * |
dc.identifier.other | OAK-10227 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/223837 | - |
dc.description.abstract | A novel divergent tandem one-pot method for the synthesis of 3,5,6-trisubstituted 1H-pyrimidin-2,4-dione derivatives is developed. In the presence of 10 mol % of Cu(OAc)2, the α-substituted Blaise reaction intermediates (R2 ≠ H) reacted with isocyanates chemoselectively to afford pyrimidin-2,4-diones, whereas the α-unsubstituted Blaise reaction intermediate (R2 = H) showed a propensity to be a C-nucleophile toward electrophiles, permitting the installation of different functionalities at the 5-position through sequential tandem reactions. © 2013 American Chemical Society. | * |
dc.language | English | * |
dc.title | An expedient and divergent tandem one-pot synthesis of pyrimidin-2,4-diones using the blaise reaction intermediate | * |
dc.type | Article | * |
dc.relation.issue | 12 | * |
dc.relation.volume | 15 | * |
dc.relation.index | SCI | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 3162 | * |
dc.relation.lastpage | 3165 | * |
dc.relation.journaltitle | Organic Letters | * |
dc.identifier.doi | 10.1021/ol401389j | * |
dc.identifier.wosid | WOS:000320979000069 | * |
dc.identifier.scopusid | 2-s2.0-84879349206 | * |
dc.author.google | Chun Y.S. | * |
dc.author.google | Xuan Z. | * |
dc.author.google | Kim J.H. | * |
dc.author.google | Lee S.-G. | * |
dc.contributor.scopusid | 이상기(15082786300) | * |
dc.contributor.scopusid | 김주현(57207894284) | * |
dc.date.modifydate | 20240123104103 | * |