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dc.contributor.author이상기-
dc.contributor.author김주현-
dc.date.accessioned2016-08-28T10:08:10Z-
dc.date.available2016-08-28T10:08:10Z-
dc.date.issued2013-
dc.identifier.issn1523-7060-
dc.identifier.otherOAK-10227-
dc.identifier.urihttp://dspace.ewha.ac.kr/handle/2015.oak/223837-
dc.description.abstractA novel divergent tandem one-pot method for the synthesis of 3,5,6-trisubstituted 1H-pyrimidin-2,4-dione derivatives is developed. In the presence of 10 mol % of Cu(OAc)2, the α-substituted Blaise reaction intermediates (R2 ≠ H) reacted with isocyanates chemoselectively to afford pyrimidin-2,4-diones, whereas the α-unsubstituted Blaise reaction intermediate (R2 = H) showed a propensity to be a C-nucleophile toward electrophiles, permitting the installation of different functionalities at the 5-position through sequential tandem reactions. © 2013 American Chemical Society.-
dc.languageEnglish-
dc.titleAn expedient and divergent tandem one-pot synthesis of pyrimidin-2,4-diones using the blaise reaction intermediate-
dc.typeArticle-
dc.relation.issue12-
dc.relation.volume15-
dc.relation.indexSCI-
dc.relation.indexSCIE-
dc.relation.indexSCOPUS-
dc.relation.startpage3162-
dc.relation.lastpage3165-
dc.relation.journaltitleOrganic Letters-
dc.identifier.doi10.1021/ol401389j-
dc.identifier.wosidWOS:000320979000069-
dc.identifier.scopusid2-s2.0-84879349206-
dc.author.googleChun Y.S.-
dc.author.googleXuan Z.-
dc.author.googleKim J.H.-
dc.author.googleLee S.-G.-
dc.contributor.scopusid이상기(15082786300)-
dc.date.modifydate20201102081004-
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자연과학대학 > 화학·나노과학전공 > Journal papers
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