Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 김성진 | * |
dc.contributor.author | 김영미 | * |
dc.date.accessioned | 2016-08-28T10:08:09Z | - |
dc.date.available | 2016-08-28T10:08:09Z | - |
dc.date.issued | 2013 | * |
dc.identifier.issn | 0020-1693 | * |
dc.identifier.other | OAK-10212 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/223824 | - |
dc.description.abstract | The paddle-wheel dinuclear unit consists of two CuII ions bridged by four benzoate ligands, and these paddle-wheel [Cu2(O 2CPh)4] units are connected by various bridging ligands to form one-dimensional chained compounds formulated as [Cu2(O 2CPh)4(μ-L)] (L = 2,4-bpe (1), 3,3'3′-dipicam (3), 2,5-Me2pyz (4), pyz (5), 4,4'4′-bpy (6), and 4-pds (7)). The compound 2, formulated as [[Cu2(O2CPh) 4][Cu(O2CPh)2](μ-bpp)2], consists of alternating units of [Cu2(O2CPh)4] and [Cu(O2CPh)2] connected by via bpp. Compounds 1-5 and 7 efficiently catalyzed the transesterification of a variety of esters, while it has been reported that Cu-containing complexes or coordination polymers do not usually show catalytic activities for the transesterification reactions. Among these compounds, 2 was most effective. It has been proposed that in the transesterification reaction, a mononuclear type of Cu complex might be the major species of compound 2 in solution, while for all other compounds, a paddle-wheel unit might be the major reactive species. © 2013 Published by Elsevier B.V. | * |
dc.language | English | * |
dc.title | Catalytic transesterification reactions of one-dimensional coordination polymers containing paddle-wheel-type units connected by various bridging ligands | * |
dc.type | Article | * |
dc.relation.volume | 402 | * |
dc.relation.index | SCI | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 39 | * |
dc.relation.lastpage | 45 | * |
dc.relation.journaltitle | Inorganica Chimica Acta | * |
dc.identifier.doi | 10.1016/j.ica.2013.03.043 | * |
dc.identifier.wosid | WOS:000320651100007 | * |
dc.identifier.scopusid | 2-s2.0-84877072520 | * |
dc.author.google | Hwang I.H. | * |
dc.author.google | Jo Y.D. | * |
dc.author.google | Kim H. | * |
dc.author.google | Kim K.B. | * |
dc.author.google | Jung K.-D. | * |
dc.author.google | Kim C. | * |
dc.author.google | Kim Y. | * |
dc.author.google | Kim S.-J. | * |
dc.contributor.scopusid | 김성진(56812714700) | * |
dc.contributor.scopusid | 김영미(57207443602) | * |
dc.date.modifydate | 20240301081003 | * |