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dc.contributor.author김성진*
dc.contributor.author김영미*
dc.date.accessioned2016-08-28T10:08:09Z-
dc.date.available2016-08-28T10:08:09Z-
dc.date.issued2013*
dc.identifier.issn0020-1693*
dc.identifier.otherOAK-10212*
dc.identifier.urihttps://dspace.ewha.ac.kr/handle/2015.oak/223824-
dc.description.abstractThe paddle-wheel dinuclear unit consists of two CuII ions bridged by four benzoate ligands, and these paddle-wheel [Cu2(O 2CPh)4] units are connected by various bridging ligands to form one-dimensional chained compounds formulated as [Cu2(O 2CPh)4(μ-L)] (L = 2,4-bpe (1), 3,3'3′-dipicam (3), 2,5-Me2pyz (4), pyz (5), 4,4'4′-bpy (6), and 4-pds (7)). The compound 2, formulated as [[Cu2(O2CPh) 4][Cu(O2CPh)2](μ-bpp)2], consists of alternating units of [Cu2(O2CPh)4] and [Cu(O2CPh)2] connected by via bpp. Compounds 1-5 and 7 efficiently catalyzed the transesterification of a variety of esters, while it has been reported that Cu-containing complexes or coordination polymers do not usually show catalytic activities for the transesterification reactions. Among these compounds, 2 was most effective. It has been proposed that in the transesterification reaction, a mononuclear type of Cu complex might be the major species of compound 2 in solution, while for all other compounds, a paddle-wheel unit might be the major reactive species. © 2013 Published by Elsevier B.V.*
dc.languageEnglish*
dc.titleCatalytic transesterification reactions of one-dimensional coordination polymers containing paddle-wheel-type units connected by various bridging ligands*
dc.typeArticle*
dc.relation.volume402*
dc.relation.indexSCI*
dc.relation.indexSCIE*
dc.relation.indexSCOPUS*
dc.relation.startpage39*
dc.relation.lastpage45*
dc.relation.journaltitleInorganica Chimica Acta*
dc.identifier.doi10.1016/j.ica.2013.03.043*
dc.identifier.wosidWOS:000320651100007*
dc.identifier.scopusid2-s2.0-84877072520*
dc.author.googleHwang I.H.*
dc.author.googleJo Y.D.*
dc.author.googleKim H.*
dc.author.googleKim K.B.*
dc.author.googleJung K.-D.*
dc.author.googleKim C.*
dc.author.googleKim Y.*
dc.author.googleKim S.-J.*
dc.contributor.scopusid김성진(56812714700)*
dc.contributor.scopusid김영미(57207443602)*
dc.date.modifydate20240301081003*
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자연과학대학 > 화학·나노과학전공 > Journal papers
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