Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 이상기 | * |
dc.contributor.author | 이준희 | * |
dc.date.accessioned | 2016-08-28T10:08:06Z | - |
dc.date.available | 2016-08-28T10:08:06Z | - |
dc.date.issued | 2013 | * |
dc.identifier.issn | 2041-6520 | * |
dc.identifier.other | OAK-10175 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/223790 | - |
dc.description.abstract | A pair of iridium-catalyzed regiospecific and stereospecific reactions of the carbonates of γ-hydroxy α,β-unsaturated esters were developed. The reaction pathways are strongly affected by the choice of amines employed. A diverse range of γ-substituted α,β-unsaturated γ-amino esters were prepared in excellent yields with various amine nucleophiles such as benzylamine, diallylamine, morpholine, aniline and N-methylaniline. Substitution at the γ-position was well tolerated, encompassing alkyl, aryl and heteroaryl substituents. Enantioenriched (E)-α,β-unsaturated γ-amino esters could also be synthesized from the corresponding enantioenriched allylic carbonates with complete chirality transfer. In sharp contrast, a series of 3,4-disubstituted oxazolidin-2-ones were obtained by using allylamine as a nucleophile. © 2013 The Royal Society of Chemistry. | * |
dc.language | English | * |
dc.title | Iridium-catalyzed regiospecific and stereospecific allylic amination for the syntheses of α,β-unsaturated γ-amino esters and the bifurcation of the reaction pathway leading to the formation of oxazolidin-2-ones | * |
dc.type | Article | * |
dc.relation.issue | 7 | * |
dc.relation.volume | 4 | * |
dc.relation.index | SCI | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 2922 | * |
dc.relation.lastpage | 2927 | * |
dc.relation.journaltitle | Chemical Science | * |
dc.identifier.doi | 10.1039/c3sc50901j | * |
dc.identifier.wosid | WOS:000319940400028 | * |
dc.identifier.scopusid | 2-s2.0-84878796950 | * |
dc.author.google | Lee J.H. | * |
dc.author.google | Lee S.-G. | * |
dc.contributor.scopusid | 이상기(15082786300) | * |
dc.date.modifydate | 20240123104103 | * |