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An accurate expression for the rates of diffusion-influenced bimolecular reactions with long-range reactivity

Title
An accurate expression for the rates of diffusion-influenced bimolecular reactions with long-range reactivity
Authors
Son C.Y.Kim J.Kim J.-H.Kim J.S.Lee S.
Ewha Authors
김준수
SCOPUS Author ID
김준수scopus
Issue Date
2013
Journal Title
Journal of Chemical Physics
ISSN
0021-9606JCR Link
Citation
vol. 138, no. 16
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
By using the recently developed method for solving the Fredholm integral equations of the second kind, we derive a very accurate expression for the steady-state rate constant of diffusion-influenced bimolecular reactions involving long-range reactivity. We consider the general case in which the reactants interact via an arbitrary central potential and hydrodynamic interaction. The rate expression becomes exact in the two opposite limits of small and large reactivity, and also performs very well in the intermediate regime. © 2013 AIP Publishing LLC.
DOI
10.1063/1.4802584
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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