View : 19 Download: 0

A multifunction Pd/Sc(OTf)3/ionic liquid catalyst system for the tandem one-pot conversion of phenol to ε-caprolactam

Title
A multifunction Pd/Sc(OTf)3/ionic liquid catalyst system for the tandem one-pot conversion of phenol to ε-caprolactam
Authors
Shin J.Y.Jung D.J.Lee S.-G.
Ewha Authors
이상기
SCOPUS Author ID
이상기scopus
Issue Date
2013
Journal Title
ACS Catalysis
ISSN
2155-5435JCR Link
Citation
vol. 3, no. 4, pp. 525 - 528
Indexed
SCIE; SCOPUS WOS scopus
Abstract
A multifunction Pd/Sc(OTf)3/ionic liquid catalyst for the tandem one-pot conversion of phenol to ε-caprolactam is reported. Pd and Sc(OTf)3 cooperate to catalyze the hydrogenation of phenol to cyclohexanone with excellent conversion (>99.9%) and selectivity (>99.9%), whereas Sc(OTf)3 and an ionic liquid, [bmim][PF6], cooperate to catalyze the tandem transformation of the resulting cyclohexanone to cyclohexanone oxime and the Beckmann rearrangement affording ε-caprolactam. © 2013 American Chemical Society.
DOI
10.1021/cs400009w
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
Files in This Item:
There are no files associated with this item.
Export
RIS (EndNote)
XLS (Excel)
XML


qrcode

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

BROWSE