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Electron-transfer properties of a nonheme manganese(iv)-oxo complex acting as a stronger one-electron oxidant than the iron(iv)-oxo analogue

Title
Electron-transfer properties of a nonheme manganese(iv)-oxo complex acting as a stronger one-electron oxidant than the iron(iv)-oxo analogue
Authors
Yoon H.Morimoto Y.Lee Y.-M.Nam W.Fukuzumi S.
Ewha Authors
남원우Shunichi Fukuzumi이용민
SCOPUS Author ID
남원우scopus; Shunichi Fukuzumiscopus; 이용민scopusscopus
Issue Date
2012
Journal Title
Chemical Communications
ISSN
1359-7345JCR Link
Citation
vol. 48, no. 91, pp. 11187 - 11189
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
Electron-transfer properties of a nonheme Mn(iv)-oxo complex, [(Bn-TPEN)MnIV(O)]2+, reveals that Mn(iv)-oxo complex acts as a stronger one-electron oxidant than the Fe(iv)-oxo analogue. As a result, an electron transfer process in N-dealkylation has been detected by a transient radical cation intermediate, para-Me-DMA+, in the oxidation of para-Me-DMA by [(Bn-TPEN)MnIV(O)]2+. © 2012 The Royal Society of Chemistry.
DOI
10.1039/c2cc36291k
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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