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Rational design of a phthalocyanine-perylenediimide dyad with a long-lived charge-separated state

Title
Rational design of a phthalocyanine-perylenediimide dyad with a long-lived charge-separated state
Authors
Blas-Ferrando V.M.Ortiz J.Bouissane L.Ohkubo K.Fukuzumi S.Fernandez-Lazaro F.Sastre-Santos A.
Ewha Authors
Shunichi Fukuzumi
SCOPUS Author ID
Shunichi Fukuzumiscopus
Issue Date
2012
Journal Title
Chemical Communications
ISSN
1359-7345JCR Link
Citation
vol. 48, no. 50, pp. 6241 - 6243
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
A new ZnPc-PDI dyad presenting for the first time a charge-separated state lower in energy than the triplet excited state of the ZnPc and PDI has been synthesized. The rational design implies the substitution of the ZnPc with phenoxy groups and the bay substitution of the PDI with sulfonyl substituents. The lifetime of the charge-separated state was 72 μs. © The Royal Society of Chemistry 2012.
DOI
10.1039/c2cc31087b
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자연과학대학 > 화학·나노과학전공 > Journal papers
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