Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 김진흥 | - |
dc.date.accessioned | 2016-08-28T12:08:32Z | - |
dc.date.available | 2016-08-28T12:08:32Z | - |
dc.date.issued | 2011 | - |
dc.identifier.issn | 0253-2964 | - |
dc.identifier.other | OAK-8181 | - |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/222117 | - |
dc.description.abstract | To quantify the presence of mercuric ions in aqueous solution, double-stranded DNA (dsDNA) of poly(dT) was employed using a light switch compound, Ru(phen) 2(dppz) 2+ (1) which is reported to intercalate into dsDNA of a right-handed B-form. Addition of mercuric ions induced the dehybridization of poly(dT)•poly(dA) duplexes to form a hairpin structure of poly(dT) at room temperature and the metal-to-ligand charge transfer emission derived from the intercalation of 1 was reduced due to the dehybridization of dsDNA. As the concentration of Hg 2+ was increased, the emission of 1 progressively decreased. This label-free emission method had a detection limit of 0.2 nM. Other metal ions, such as K +, Ag +, Ca 2+, Mg 2+, Zn 2+, Mn 2+, Co 2+, Ni 2+, Cu 2+, Cd 2+, Cr 3+, Fe 3+, had no significant effect on reducing emission. This emission method can differentiate matched and mismatched poly(dT) sequences based on the emission intensity of dsDNA. | - |
dc.language | English | - |
dc.title | Emission detection of mercuric ions in aqueous media based-on dehybridization of DNA duplexes | - |
dc.type | Article | - |
dc.relation.issue | 9 | - |
dc.relation.volume | 32 | - |
dc.relation.index | SCIE | - |
dc.relation.index | SCOPUS | - |
dc.relation.index | KCI | - |
dc.relation.startpage | 3223 | - |
dc.relation.lastpage | 3228 | - |
dc.relation.journaltitle | Bulletin of the Korean Chemical Society | - |
dc.identifier.doi | 10.5012/bkcs.2011.32.9.3223 | - |
dc.identifier.wosid | WOS:000297384000006 | - |
dc.identifier.scopusid | 2-s2.0-80053102802 | - |
dc.author.google | Oh B.N. | - |
dc.author.google | Wu Q. | - |
dc.author.google | Cha M.S. | - |
dc.author.google | Kang H.K. | - |
dc.author.google | Kim J.A. | - |
dc.author.google | Kim K.Y. | - |
dc.author.google | Rajkumar E. | - |
dc.author.google | Kim J. | - |
dc.contributor.scopusid | 김진흥(8580015800) | - |
dc.date.modifydate | 20170601134213 | - |