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Facile preparation of PbTiO3 nanodot arrays: Combining nanohybridization with vapor phase reaction sputtering

Title
Facile preparation of PbTiO3 nanodot arrays: Combining nanohybridization with vapor phase reaction sputtering
Authors
Kim J.Hong J.Park M.Zhe W.Kim D.Jang Y.J.Kim D.H.No K.
Ewha Authors
김동하
SCOPUS Author ID
김동하scopus
Issue Date
2011
Journal Title
Advanced Functional Materials
ISSN
1616-301XJCR Link
Citation
vol. 21, no. 22, pp. 4277 - 4284
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
A facile route is presented for the fabrication of spherical PbTiO 3 (PTO) nanodot arrays on platinized silicon substrates using PbO vapor phase reaction sputtering on micellar monolayer films of polystyrene-block-poly(ethylene oxide) (PS-b-PEO) loaded with TiO2 sol-gel precursor. Short exposure to PbO transforms the amorphous TiO 2 into polycrystalline PTO, while keeping the inherent size and periodicity of TiO2 nanodots. HRTEM images show that the spherical PTO nanodots, with an average size and height of 63 nm and 40 nm, respectively, are fixed on the Pt supported by residual carbon. XPS narrow scan spectra of Ti 2p and O 1s strongly verify the evolution of chemical identity and the reduction of the Ti-O binding energy from TiO2 to PTO. The amplitude and phase images of piezoelectric force microscopy (PFM) confirm a multidomain structure attributed by the crystalline orientation of the PTO nanodots. Furthermore, the discrete PTO nanodots show remarkable switching properties due to the low strain field induced by the small lateral size, and the absence of domain pinning effects by grain boundary. Ferroelectric PbTiO3 nanodot arrays are fabricated on platinized silicon substrates using PbO vapor phase reaction sputtering on micellar monolayer films of polystyrene-block-poly(ethylene oxide) (PS-b-PEO) loaded with a TiO2 sol-gel precursor. This new fabrication route encourages their application in next-generation memory and data-storage devices with Tb inch-2 density. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
DOI
10.1002/adfm.201101033
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자연과학대학 > 화학·나노과학전공 > Journal papers
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