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Control of electron-transfer reduction by protonation of zinc octabutoxyphthalocyanine assisted by intramolecular hydrogen bonding

Title
Control of electron-transfer reduction by protonation of zinc octabutoxyphthalocyanine assisted by intramolecular hydrogen bonding
Authors
Honda T.Kojima T.Fukuzumi S.
Ewha Authors
Shunichi Fukuzumi
SCOPUS Author ID
Shunichi Fukuzumiscopus
Issue Date
2011
Journal Title
Chemical Communications
ISSN
1359-7345JCR Link
Citation
vol. 47, no. 28, pp. 7986 - 7988
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
Facile protonation of α-octabutoxyphthalocyaninato zinc(ii) (Zn(OBu) 8Pc) occurs to afford up to tetra-protonated species stabilized by intramolecular hydrogen bonding, resulting in positive shifts of the reduction potentials of Zn(OBu) 8PcH n n+ (n = 1-4) with increasing the number of protons attached to facilitate electron-transfer reduction. © 2011 The Royal Society of Chemistry.
DOI
10.1039/c1cc12710a
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자연과학대학 > 화학·나노과학전공 > Journal papers
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