Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 김관묵 | - |
dc.date.accessioned | 2016-08-28T12:08:42Z | - |
dc.date.available | 2016-08-28T12:08:42Z | - |
dc.date.issued | 2011 | - |
dc.identifier.issn | 0253-2964 | - |
dc.identifier.other | OAK-7603 | - |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/221644 | - |
dc.description.abstract | Novel binol-based uryl and guanidinium receptors having higher ring conjugation at the periphery of the hydrogen bonding donor sites have been synthesized and utilized to study the enantioselective recognition of 1,2-aminoalcohols and chirality conversion of natural amino acids via imine bond formation. There is a remarkable decrease in the stereoselectivites as the conjugation increases at the periphery of hydrogen bonding donor sites. The guanidinium-based receptors show more selectivity towards the amino alcohol than that of the uryl based ones due to its charge reinforced hydrogen bonds. The conversion efficiency of L-amino acids to Damino acids by the uryl-based receptors is higher than that of the guanidinium-based ones. | - |
dc.language | English | - |
dc.title | Enantioselective recognition of amino alcohols and amino acids by chiral binol-based aldehydes with conjugated rings at the hydrogen bonding donor sites | - |
dc.type | Article | - |
dc.relation.issue | 4 | - |
dc.relation.volume | 32 | - |
dc.relation.index | SCI | - |
dc.relation.index | SCIE | - |
dc.relation.index | SCOPUS | - |
dc.relation.index | KCI | - |
dc.relation.startpage | 1263 | - |
dc.relation.lastpage | 1267 | - |
dc.relation.journaltitle | Bulletin of the Korean Chemical Society | - |
dc.identifier.doi | 10.5012/bkcs.2011.32.4.1263 | - |
dc.identifier.wosid | WOS:000290366200030 | - |
dc.identifier.scopusid | 2-s2.0-79954627730 | - |
dc.author.google | Kim J. | - |
dc.author.google | Nandhakumar R. | - |
dc.author.google | Kim K.M. | - |
dc.contributor.scopusid | 김관묵(35484385500) | - |
dc.date.modifydate | 20230208104137 | - |