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Photocatalytic production of hydrogen by disproportionation of one-electron-reduced rhodium and iridium-ruthenium complexes in water

Title
Photocatalytic production of hydrogen by disproportionation of one-electron-reduced rhodium and iridium-ruthenium complexes in water
Authors
Fukuzumi S.Kobayashi T.Suenobu T.
Ewha Authors
Shunichi Fukuzumi
SCOPUS Author ID
Shunichi Fukuzumiscopus
Issue Date
2011
Journal Title
Angewandte Chemie - International Edition
ISSN
1433-7851JCR Link
Citation
vol. 50, no. 3, pp. 728 - 731
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
One at a time: A rhodium aqua complex and a heterodinuclear iridium-ruthenium complex (see picture) act as effective catalysts for the photocatalytic two-electron reduction of protons. Hydrogen is produced with the aid of a photosensitizer and an electron donor by disproportionation of the corresponding one-electron-reduced metal complexes. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
DOI
10.1002/anie.201004876
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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