Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 남원우 | * |
dc.contributor.author | Shunichi Fukuzumi | * |
dc.contributor.author | 이용민 | * |
dc.date.accessioned | 2016-08-28T12:08:34Z | - |
dc.date.available | 2016-08-28T12:08:34Z | - |
dc.date.issued | 2010 | * |
dc.identifier.issn | 0002-7863 | * |
dc.identifier.other | OAK-6791 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/220967 | - |
dc.description.abstract | Iron(III)-superoxo intermediates are believed to play key roles in oxygenation reactions by non-heme iron enzymes. We now report that a non-heme iron(II) complex activates O2 and generates its corresponding iron(IV)-oxo complex in the presence of substrates with weak C-H bonds (e.g., olefins and alkylaromatic compounds). We propose that a putative iron(III)-superoxo intermediate initiates the O2-activation chemistry by abstracting a H atom from the substrate, with subsequent generation of a high-valent iron(IV)-oxo intermediate from the resulting iron(III)-hydroperoxo species. © 2010 American Chemical Society. | * |
dc.language | English | * |
dc.title | Dioxygen activation by a non-heme iron(II) complex: Formation of an iron(IV)-oxo complex via C-H activation by a putative iron(III)-superoxo species | * |
dc.type | Article | * |
dc.relation.issue | 31 | * |
dc.relation.volume | 132 | * |
dc.relation.index | SCI | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 10668 | * |
dc.relation.lastpage | 10670 | * |
dc.relation.journaltitle | Journal of the American Chemical Society | * |
dc.identifier.doi | 10.1021/ja103903c | * |
dc.identifier.wosid | WOS:000280692200020 | * |
dc.identifier.scopusid | 2-s2.0-77955401788 | * |
dc.author.google | Lee Y.-M. | * |
dc.author.google | Hong S. | * |
dc.author.google | Morimoto Y. | * |
dc.author.google | Shin W. | * |
dc.author.google | Fukuzumi S. | * |
dc.author.google | Nam W. | * |
dc.contributor.scopusid | 남원우(7006569723) | * |
dc.contributor.scopusid | Shunichi Fukuzumi(35430038100;58409757400) | * |
dc.contributor.scopusid | 이용민(36546331100;35233855500;57192113229) | * |
dc.date.modifydate | 20240130092215 | * |