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A new hexanuclear rhenium cluster complex with six terminal acetate ligands: Synthesis, structure, and properties of K4Re 6S8(CH3COO)6 · H2O

Title
A new hexanuclear rhenium cluster complex with six terminal acetate ligands: Synthesis, structure, and properties of K4Re 6S8(CH3COO)6 · H2O
Authors
Brylev K.A.Mironov Y.V.Fedorov V.E.Kim S.-J.Pietzsch H.-J.Stephan H.Ito A.Kitamura N.
Ewha Authors
김성진
SCOPUS Author ID
김성진scopus
Issue Date
2010
Journal Title
Inorganica Chimica Acta
ISSN
0020-1693JCR Link
Citation
vol. 363, no. 11, pp. 2686 - 2691
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
A room-temperature reaction between [Re6S8(OH) 6]4- and acetic acid in an aqueous solution resulted in the substitution of all terminal hydroxo groups by acetate ligands, affording a new hexanuclear anionic rhenium cluster complex [Re6S 8(CH3COO)6]4-. The complex was isolated as a potassium salt with the composition of K4[Re 6S8(CH3COO)6].8H2O (1) and characterized by X-ray single-crystal diffraction and elemental analyses, IR, 1H NMR, UV-Vis, and luminescence spectroscopies. © 2010 Elsevier B.V. All rights reserved.
DOI
10.1016/j.ica.2010.04.042
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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