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Thioether S-ligation in a side-on μ-η2:η2- peroxodicopper(ii) complex

Title
Thioether S-ligation in a side-on μ-η2:η2- peroxodicopper(ii) complex
Authors
Park G.Y.Lee Y.Lee D.-H.Woertink J.S.Narducci Sarjeant A.A.Solomon E.I.Karlin K.D.
Ewha Authors
Kenneth D. Karlin
Issue Date
2010
Journal Title
Chemical Communications
ISSN
1359-7345JCR Link
Citation
vol. 46, no. 1, pp. 91 - 93
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
[(ANS)CuI(CH3CN)]+ reacts with O 2 giving [{(ANS)CuII}2(μ-η2: η2-O2 2-)]2+, νO-O = 731 cm-1, shown to possess S-thioether ligation, based on comparisons with analogues having all N-ligands or a -S(Ph) group. The finding is a rare occurrence and new for side-on O2 2- binding. © 2010 The Royal Society of Chemistry.
DOI
10.1039/b918616f
Appears in Collections:
일반대학원 > 바이오융합과학과 > Journal papers
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