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Electronic structure and local atomic arrangement of transition metal ions in nanoporous iron-substituted nickel phosphates, VSB-1 and VSB-5

Title
Electronic structure and local atomic arrangement of transition metal ions in nanoporous iron-substituted nickel phosphates, VSB-1 and VSB-5
Authors
Kim T.W.Oh E.-J.Jhung S.H.Chang J.-S.Hwang S.-J.
Ewha Authors
황성주
SCOPUS Author ID
황성주scopus
Issue Date
2010
Journal Title
Journal of Nanoscience and Nanotechnology
ISSN
1533-4880JCR Link
Citation
vol. 10, no. 1, pp. 240 - 245
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
The electronic structure and local atomic arrangement of transition metal ions in nanoporous iron- substituted nickel phosphates VSB-1 and VSB-5 have been investigated using X-ray absorption near-edge structure (XANES) spectroscopy at Fe K- and Ni K-edges. The Fe K-edge XANES study clearly demonstrated that substituted iron ions were stabilized in octahedral nickel sites of nanoporous nickel phosphate lattice. A comparison with several Fe-references revealed that the substituted irons have mixed Fe 2+/Fe 3+ oxidation state with the average valence of +2.8-3. According to the Ni K-edge XANES analysis, the aliovalent substitution of Ni 2+ with Fe 2+/Fe 2+ induced a slight reduction of divalent nickel ions in VSB-5 to meet a charge balance. On the contrary, Fe substitution for the VSB-1 phase did not cause notable decrease in the oxidation state of nickel ions, which would be related either to the accompanying decrease of pentavalent phosphorus cations or to the increase of oxygen anions. In conclusion, the present findings clearly demonstrated that the nanoporous lattice of nickel phosphate can accommodate effectively iron ions in its octahedral nickel sites. Copyright © 2010 American Scientific Publishers. All rights reserved.
DOI
10.1166/jnn.2010.1515
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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