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dc.contributor.author김성진*
dc.contributor.author김영미*
dc.date.accessioned2016-08-28T12:08:18Z-
dc.date.available2016-08-28T12:08:18Z-
dc.date.issued2009*
dc.identifier.issn0020-1693*
dc.identifier.otherOAK-5818*
dc.identifier.urihttps://dspace.ewha.ac.kr/handle/2015.oak/220214-
dc.description.abstractFive polymeric metal(II)-benzoate complexes of formula [Mn(O2CPh)2(CH3OH)2(bpa)]n (1-Mn), [Co(O2CPh)2(H2O)(bpa)1.5]n (2-Co), [Ni(O2CPh)2(H2O)(bpa)1.5]n (3-Ni), [Cu(O2CPh)2(CH3OH)2(bpa)]n (4-Cu), and [Cd(O2CPh)2(bpa)1.5]n (6-Cd) have been synthesized and characterized (bpa = 1,2-bis(4-pyridyl)ethane). They showed two kinds of structures: parallelogram-like two-dimensional sheets for Co, Ni, and Cd, and one-dimensional chains for Mn, Cu, and Zn. Since similar structures provide similar coordination geometries, the structures depend on the coordination geometries of metal ions. The compounds 1-Mn, 2-Co, 4-Cu, 5-Zn, and 6-Cd have catalyzed efficiently the transesterification of a variety of esters, while 3-Ni has displayed a very slow conversion. The reactivity of catalyst 6-Cd containing Cd ion, well known as an inert metal ion for the ligand substitution, was found to be comparable to that of 5-Zn. The reactivities of the compounds used in this study are in the order of 5-Zn > 6-Cd > 1-Mn > 4-Cu > 2-Co ≫ 3-Ni, indicating that the non-redox metal-containing compounds (5-Zn and 6-Cd) show better activity than the redox-active metal-containing compounds (1-Mn, 4-Cu, 2-Co, and 3-Ni). © 2009 Elsevier B.V. All rights reserved.*
dc.languageEnglish*
dc.titleConstruction of crystal structures of metal(II)-benzoates (M = Mn, Ni, Co, Cu, Zn, and Cd) and 1,2-bis(4-pyridyl)ethane: Effects of metal coordination modes and their catalytic activities*
dc.typeArticle*
dc.relation.issue11*
dc.relation.volume362*
dc.relation.indexSCI*
dc.relation.indexSCIE*
dc.relation.indexSCOPUS*
dc.relation.startpage4119*
dc.relation.lastpage4126*
dc.relation.journaltitleInorganica Chimica Acta*
dc.identifier.doi10.1016/j.ica.2009.06.008*
dc.identifier.wosidWOS:000268663900034*
dc.identifier.scopusid2-s2.0-67849088518*
dc.author.googleKim S.H.*
dc.author.googlePark B.K.*
dc.author.googleSong Y.J.*
dc.author.googleYu S.M.*
dc.author.googleKoo H.G.*
dc.author.googleKim E.Y.*
dc.author.googlePoong J.I.*
dc.author.googleLee J.H.*
dc.author.googleKim C.*
dc.author.googleKim S.-J.*
dc.author.googleKim Y.*
dc.contributor.scopusid김성진(56812714700)*
dc.contributor.scopusid김영미(57207443602)*
dc.date.modifydate20240301081003*
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자연과학대학 > 화학·나노과학전공 > Journal papers
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