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Hydrogen atom abstraction and hydride transfer reactions by iron(IV)-oxo porphyrins

Title
Hydrogen atom abstraction and hydride transfer reactions by iron(IV)-oxo porphyrins
Authors
Jeong Y.J.Kang Y.Han A.-R.Lee Y.-M.Kotani H.Fukuzumi S.Nam W.
Ewha Authors
남원우Shunichi Fukuzumi이용민
SCOPUS Author ID
남원우scopus; Shunichi Fukuzumiscopus; 이용민scopusscopus
Issue Date
2008
Journal Title
Angewandte Chemie - International Edition
ISSN
1433-7851JCR Link
Citation
vol. 47, no. 38, pp. 7321 - 7324
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
(Chemical Equation Presented) True identity revealed: The C-H bond activation of alkyl aromatics by synthetic iron(IV)-oxo porphyrin species and the hydride transfer of NADH analogues to them occur through H-atom abstraction and proton-coupled electron-transfer mechanisms, respectively. Mechanistic studies revealed that iron(IV)-oxo porphyrin π, not iron(IV)-oxo porphyrin pradical cations, are the true oxidant. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
DOI
10.1002/anie.200802346
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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