Full metadata record
DC Field | Value | Language |
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dc.contributor.author | 양인상 | - |
dc.date.accessioned | 2016-08-28T11:08:07Z | - |
dc.date.available | 2016-08-28T11:08:07Z | - |
dc.date.issued | 2006 | - |
dc.identifier.issn | 0374-4884 | - |
dc.identifier.other | OAK-3437 | - |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/219728 | - |
dc.description.abstract | We report significant differences in the Raman spectra of two different kinds of CaB 6 single crystals grown from boron with a purity of 99.9 % (3N) or 99.9999 % (6N). Our Raman spectra of CaB 6 (3N) show peaks around 781 (T 2g), 1141 (E g), and 1283 cm -1 (A 1g), and they are very similar to previous Raman spectra of CaB 6. The E g mode shows a characteristic double-peak feature due to an additional weak broad peak centered around 1158 cm -1. However, the Raman spectra of CaB 6 (6N) show sharp peaks around 771 (T 2g), 1137 (E g), and 1266 cm -1 (A 1g). The peak frequencies are down shifted as much as ∼17 cm -1. In addition, no additional peak feature is observed for the E g mode so that the mode is symmetric in the case of CaB 6 (6N). The X-ray powder diffraction patterns for both CaB 6 (3N) and CaB 6 (6N) show that the lattice parameters are essentially the same. The majority of the impurity in the 99.9 %-pure (3N) boron is C. Thus, we doped CaB 6 (6N) with C, making Ca(B 0.995C 0.005) 6, and looked for differences in the Raman spectra. The Raman spectra of Ca(B 0.995C 0.005) 6 are nearly identical to those of CaB 6 (6N), indicating that the differences between the Raman spectra of CaB 6 (3N) and CaB 6 (6N) are not due to a C impurity. The Raman results show that the presence of impurities, not the amount of them, is enough to trigger local symmetry breaking in CaB 6. The broadening of T 2g, the additional E g2 mode and the asymmetry of A 1g in CaB 6 (3N) can be understood in terms of the symmetry of the arrangements of the boron octahedra lowered by local symmetry breaking. | - |
dc.language | English | - |
dc.title | Boron-purity-dependent Raman spectra of CaB 6 | - |
dc.type | Article | - |
dc.relation.issue | 1 | - |
dc.relation.volume | 49 | - |
dc.relation.index | SCI | - |
dc.relation.index | SCIE | - |
dc.relation.index | SCOPUS | - |
dc.relation.index | KCI | - |
dc.relation.startpage | L1 | - |
dc.relation.lastpage | L5 | - |
dc.relation.journaltitle | Journal of the Korean Physical Society | - |
dc.identifier.wosid | WOS:000239073100001 | - |
dc.identifier.scopusid | 2-s2.0-33747058272 | - |
dc.author.google | Song M. | - |
dc.author.google | Yang I.-S. | - |
dc.author.google | Kim J.Y. | - |
dc.author.google | Cho B.K. | - |
dc.contributor.scopusid | 양인상(7101797839) | - |
dc.date.modifydate | 20230210140835 | - |