Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 고수영 | - |
dc.date.accessioned | 2016-08-28T11:08:18Z | - |
dc.date.available | 2016-08-28T11:08:18Z | - |
dc.date.issued | 2003 | - |
dc.identifier.issn | 0018-019X | - |
dc.identifier.other | OAK-1425 | - |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/219189 | - |
dc.description.abstract | The Baylis-Hillman reaction is accelerated in the presence of ionic liquids. Of various 1-butyl-3-methylimidazolium (bmim)-based ionic liquids tested, [bmim][PF6] has been found to result in the highest rate increase. In the company of Lewis acid and H-bond-donor additives, the reaction rates further improve, albeit only modestly. A preparatively useful Baylis-Hillman procedure prescribes the use of [bmim][PF6] with La(OTf)3 and 2,2′2″-nitrilotris [ethanol], in which the net effect of the ionic liquid is to bring about a more than twofold rate increase over the otherwise same reaction in MeCN. | - |
dc.language | English | - |
dc.title | Acceleration of the Baylis-Hillman reaction in the presence of ionic liquids | - |
dc.type | Article | - |
dc.relation.issue | 3 | - |
dc.relation.volume | 86 | - |
dc.relation.index | SCI | - |
dc.relation.index | SCIE | - |
dc.relation.index | SCOPUS | - |
dc.relation.startpage | 894 | - |
dc.relation.lastpage | 899 | - |
dc.relation.journaltitle | Helvetica Chimica Acta | - |
dc.identifier.doi | 10.1002/hlca.200390087 | - |
dc.identifier.wosid | WOS:000182095900034 | - |
dc.identifier.scopusid | 2-s2.0-0037260458 | - |
dc.author.google | Kim E.J. | - |
dc.author.google | Ko S.Y. | - |
dc.author.google | Song C.E. | - |
dc.contributor.scopusid | 고수영(7403325351) | - |
dc.date.modifydate | 20230208103927 | - |