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Biomimetic alkane hydroxylation by cobalt(III) porphyrin complex and m-chloroperbenzoic acid

Title
Biomimetic alkane hydroxylation by cobalt(III) porphyrin complex and m-chloroperbenzoic acid
Authors
Nam W.Kim I.Kim Y.Kim C.
Ewha Authors
남원우김영미
SCOPUS Author ID
남원우scopus; 김영미scopus
Issue Date
2001
Journal Title
Chemical Communications
ISSN
1359-7345JCR Link
Citation
no. 14, pp. 1262 - 1263
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
The catalytic hydroxylation of alkanes by an electron-deficient cobalt(III) porphyrin complex and m-chloroperbenzoic acid yielded alcohols as major products with a high k H/k D value, > 99% retention of stereochemistry, and a high regioselectivity; a high-valent cobalt - oxo porphyrin complex was suggested as a reactive hydroxylating intermediate.
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자연과학대학 > 화학·나노과학전공 > Journal papers
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