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Temperature effect on the epoxidation of olefins by an iron(III) porphyrin complex and tert-alkyl hydroperoxides

Title
Temperature effect on the epoxidation of olefins by an iron(III) porphyrin complex and tert-alkyl hydroperoxides
Authors
Nam W.Oh S.-Y.Mi Hee LimChoi M.-H.Han S.-Y.Jhon G.-J.
Ewha Authors
전길자남원우한소엽
SCOPUS Author ID
전길자scopus; 남원우scopus; 한소엽scopus
Issue Date
2000
Journal Title
Chemical Communications
ISSN
1359-7345JCR Link
Citation
no. 18, pp. 1787 - 1788
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
An electron-deficient iron porphyrin complex catalyzes the epoxidation of olefins by tert-alkyl hydroperoxides via radical-free oxidation reactions in aprotic solvent; the epoxidation reactions were markedly influenced by reaction temperature and high yields of epoxide products were obtained with retention of stereospecificity at low temperature.
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자연과학대학 > 화학·나노과학전공 > Journal papers
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