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Reversal of regioselection in the rearrangement of cinnamate diol cyclic iminocarbonates

Title
Reversal of regioselection in the rearrangement of cinnamate diol cyclic iminocarbonates
Authors
Cho G.Y.Park J.N.Ko S.Y.
Ewha Authors
고수영
SCOPUS Author ID
고수영scopus
Issue Date
2000
Journal Title
Tetrahedron Letters
ISSN
0040-4039JCR Link
Citation
vol. 41, no. 11, pp. 1789 - 1792
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
The rearrangement of cinnamate diol cyclic iminocarbonates can be regioselectively controlled by using, as the nucleophile, Bu4NBr (for β[benzylic]-nitrogen regioselection) or LiI (for the α-nitrogen isomers). This discovery will expand the synthetic utilities of the cyclic iminocarbonate rearrangement and the asymmetric dihydroxylation processes. (C) 2000 Elsevier Science Ltd.
DOI
10.1016/S0040-4039(00)00017-4
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자연과학대학 > 화학·나노과학전공 > Journal papers
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