Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 황성주 | - |
dc.date.accessioned | 2016-08-27T04:08:11Z | - |
dc.date.available | 2016-08-27T04:08:11Z | - |
dc.date.issued | 2016 | - |
dc.identifier.issn | 0013-4686 | - |
dc.identifier.issn | 1873-3859 | - |
dc.identifier.other | OAK-18584 | - |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/218208 | - |
dc.description.abstract | An efficient and economical route for the synthesis of porous two-dimensional (2D) nanoplates of silicon is developed via the magnesiothermically-induced phase transition of exfoliated clay 2D nanosheets. The magnesiothermic reaction of precursor clay nanosheets prepared by the exfoliation and restacking with Mg2+ cations yields porous 2D nanoplates of elemental silicon. The variation in the Mg:SiO2 ratio has a significant effect on the porosity and connectivity of silicon nanoplates. The porous silicon nanoplates show a high discharge capacity of 2000 mAh g (1) after 50 cycles. Of prime importance is that this electrode material still retains a large discharge capacity at higher C-rates, which is unusual for the elemental silicon electrode. This is mainly attributed to the improved diffusion of lithium ions, charge-transfer kinetics, and the preservation of the electrical connection of the porous 2D plate-shaped morphology. This study highlights the usefulness of clay mineral as an economical and scalable precursor of high-performance silicon electrodes with tailorable nanostructures. (C) 2016 Elsevier Ltd. All rights reserved. | - |
dc.language | English | - |
dc.publisher | PERGAMON-ELSEVIER SCIENCE LTD | - |
dc.subject | Lithium-ion batteries | - |
dc.subject | Silicon | - |
dc.subject | 2D nanostructure | - |
dc.subject | Mesoporous materials | - |
dc.subject | Clay | - |
dc.title | Effective Chemical Route to 2D Nanostructured Silicon Electrode Material: Phase Transition from Exfoliated Clay Nanosheet to Porous Si Nanoplate | - |
dc.type | Article | - |
dc.relation.volume | 204 | - |
dc.relation.index | SCIE | - |
dc.relation.index | SCOPUS | - |
dc.relation.startpage | 60 | - |
dc.relation.lastpage | 68 | - |
dc.relation.journaltitle | ELECTROCHIMICA ACTA | - |
dc.identifier.doi | 10.1016/j.electacta.2016.04.043 | - |
dc.identifier.wosid | WOS:000376136700006 | - |
dc.identifier.scopusid | 2-s2.0-84964345820 | - |
dc.author.google | Adpakpang, Kanyaporn | - |
dc.author.google | Patil, Sharad B. | - |
dc.author.google | Oh, Seung Mi | - |
dc.author.google | Kang, Joo-Hee | - |
dc.author.google | Lacroix, Marc | - |
dc.author.google | Hwang, Seong-Ju | - |
dc.contributor.scopusid | 황성주(7404626171) | - |
dc.date.modifydate | 20190901081003 | - |