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Photoluminescent materials based on PMMA and a highly-emissive octahedral molybdenum metal cluster complex

Title
Photoluminescent materials based on PMMA and a highly-emissive octahedral molybdenum metal cluster complex
Authors
Efremova, Olga A.Brylev, Konstantin A.Vorotnikov, Yuri A.Vejsadova, LucieShestopalov, Michael A.Chimonides, Gwen F.Mikes, PetrTopham, Paul D.Kim, Sung-JinKitamura, NoboruSutherland, Andrew J.
Ewha Authors
김성진
SCOPUS Author ID
김성진scopus
Issue Date
2016
Journal Title
JOURNAL OF MATERIALS CHEMISTRY C
ISSN
2050-7526JCR Link2050-7534JCR Link
Citation
vol. 4, no. 3, pp. 497 - 503
Publisher
ROYAL SOC CHEMISTRY
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
Materials that combine photoluminescence, optical transparency and facile processability are of high importance in many applications. This article reports on the development of photoluminescent poly(methyl methacrylate) materials based on novel highly emissive anionic molybdenum cluster complex [{Mo6I8}(OTs)(6)](2-) (where OTs is the p-toluenesulfonate ion). The materials were obtained by both solution and bulk copolymerisation of methyl methacrylate and (dMDAEMA)(2)[{Mo6I8}(OTs)(6)], where dMDAEMA(+) is the polymerisable cation [2-(methacryloyloxy)ethyl]dimethyl-dodecylammonium. Evaluation of the resultant hybrid materials showed that one could combine the excellent photoluminescent properties of the cluster complex with the transparency and processability of PMMA.
DOI
10.1039/c5tc03204k
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자연과학대학 > 화학·나노과학전공 > Journal papers
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