Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 유영민 | * |
dc.date.accessioned | 2016-08-27T04:08:40Z | - |
dc.date.available | 2016-08-27T04:08:40Z | - |
dc.date.issued | 2016 | * |
dc.identifier.issn | 1615-4150 | * |
dc.identifier.issn | 1615-4169 | * |
dc.identifier.other | OAK-16184 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/217914 | - |
dc.description.abstract | Two transformations initiated by photoinduced one-electron transfer to a-bromo ketones have been demonstrated. Hantzsch esters donate one electron to alpha-bromo ketones under photoirradiation, promoting reductive debromination. Subsequent reactions of the resulting radical species of the ketones with molecular oxygen and Hantzsch esters lead to alpha-hydroxylation or debromination, respectively. The relative dominance of the two pathways depends profoundly on the reaction conditions, including solvent, O-2 levels, and the concentration of the Hantzsch esters. The synthetic protocols feature advantages because they require the environmentally benign sources, molecular oxygen and visible light. | * |
dc.language | English | * |
dc.publisher | WILEY-V C H VERLAG GMBH | * |
dc.subject | debromination | * |
dc.subject | Hantzsch esters | * |
dc.subject | hydroxylation | * |
dc.subject | photoreductants | * |
dc.title | Selective Debromination and alpha-Hydroxylation of alpha-Bromo Ketones Using Hantzsch Esters as Photoreductants | * |
dc.type | Article | * |
dc.relation.issue | 1 | * |
dc.relation.volume | 358 | * |
dc.relation.index | SCI | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 74 | * |
dc.relation.lastpage | 80 | * |
dc.relation.journaltitle | ADVANCED SYNTHESIS & CATALYSIS | * |
dc.identifier.doi | 10.1002/adsc.201500734 | * |
dc.identifier.wosid | WOS:000370256000011 | * |
dc.identifier.scopusid | 2-s2.0-84954360219 | * |
dc.author.google | Jung, Jaehun | * |
dc.author.google | Kim, Jun | * |
dc.author.google | Park, Gyurim | * |
dc.author.google | You, Youngmin | * |
dc.author.google | Cho, Eun Jin | * |
dc.contributor.scopusid | 유영민(24759463600) | * |
dc.date.modifydate | 20240422132144 | * |