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Mononuclear nonheme iron(IV)-oxo and manganese(IV)-oxo complexes in oxidation reactions: experimental results prove theoretical prediction

Title
Mononuclear nonheme iron(IV)-oxo and manganese(IV)-oxo complexes in oxidation reactions: experimental results prove theoretical prediction
Authors
Chen, JunyingCho, Kyung-BinLee, Yong-MinKwon, Yoon HyeNam, Wonwoo
Ewha Authors
남원우이용민
SCOPUS Author ID
남원우scopus; 이용민scopusscopus
Issue Date
2015
Journal Title
CHEMICAL COMMUNICATIONS
ISSN
1359-7345JCR Link1364-548XJCR Link
Citation
vol. 51, no. 66, pp. 13094 - 13097
Publisher
ROYAL SOC CHEMISTRY
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
Reactivities of mononuclear nonheme iron(IV)-oxo and manganese(IV)-oxo complexes bearing a pentadentate N4Py ligand, [(MO)-O-IV(N4Py)](2+) (M = Fe and Mn), are compared in hydrogen atom transfer (HAT) and oxygen atom transfer (OAT) reactions; theoretical and experimental results show that (FeO)-O-IV is more reactive than (MnO)-O-IV. The latter is shown to react through excited state reactivity (ESR).
DOI
10.1039/c5cc04217h
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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