View : 21 Download: 0

High-valent metal-oxo intermediates in energy demanding processes: from dioxygen reduction to water splitting

Title
High-valent metal-oxo intermediates in energy demanding processes: from dioxygen reduction to water splitting
Authors
Ray, KallolHeims, FlorianSchwalbe, MatthiasNam, Wonwoo
Ewha Authors
남원우
SCOPUS Author ID
남원우scopus
Issue Date
2015
Journal Title
CURRENT OPINION IN CHEMICAL BIOLOGY
ISSN
1367-5931JCR Link1879-0402JCR Link
Citation
vol. 25, pp. 159 - 171
Publisher
ELSEVIER SCI LTD
Indexed
SCI; SCIE; SCOPUS WOS
Abstract
Four-electron reduction of dioxygen to water and splitting of water to dioxygen are extremely important processes in the context of attaining clean renewable energy sources. High-valent metal-oxo cores are proposed as reactive intermediates in these vital processes, although they have only been isolated in extremely rare cases in the biological systems thereby making the mechanism ambiguous. Recent biomimetic studies have, however, aided in our understanding of the fundamental reactivity of the high-valent metal-oxo species in various reactions relevant to energy conversion. All these studies are summarized in the present review.
DOI
10.1016/j.cbpa.2015.01.014
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
Files in This Item:
There are no files associated with this item.
Export
RIS (EndNote)
XLS (Excel)
XML


qrcode

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

BROWSE