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The effect of solvent on the alpha-effect: C=O, P=O and SO2 centers

Title
The effect of solvent on the alpha-effect: C=O, P=O and SO2 centers
Authors
Um, IHHong, JYBuncel, E
Ewha Authors
엄익환
SCOPUS Author ID
엄익환scopusscopus
Issue Date
2001
Journal Title
CHEMICAL COMMUNICATIONS
ISSN
1359-7345JCR Link
Citation
no. 01, pp. 27 - 28
Publisher
ROYAL SOC CHEMISTRY
Indexed
SCI; SCIE; SCOPUS WOS
Abstract
The alpha -effect for the reaction of a sulfonyl ester exhibits a bell-shaped dependence of the alpha -effect on solvent composition as do the corresponding reactions with a carbonyl and a phosphinyl ester, and the magnitude of the alpha -effect is found to be dependent on the magnitude of the beta (nuc) value, suggesting TS stabilization as the cause of the alpha -effect.
DOI
10.1039/b007000i
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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