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Highly stereoselective and efficient hydrosilylation of terminal alkynes catalyzed by [RuCl2(p-cymene)](2)

Title
Highly stereoselective and efficient hydrosilylation of terminal alkynes catalyzed by [RuCl2(p-cymene)](2)
Authors
Na, YGChang, SB
Ewha Authors
장석복
Issue Date
2000
Journal Title
ORGANIC LETTERS
ISSN
1523-7060JCR Link
Citation
vol. 2, no. 13, pp. 1887 - 1889
Publisher
AMER CHEMICAL SOC
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
With [RuCl2(p-cymene)](2) as a catalyst, extremely high regio- and stereoselectivity was observed in the hydrosilylation reaction of various terminal alkynes under mild conditions to afford beta-(Z)-vinylsilanes in excellent yields. A dramatic directing effect was also observed when alkynes having a hydroxyl group at the beta position to the triple bond were employed as a substrate, and in these cases regioisomeric alpha-vinylsilanes were generated with excellent selectivity.
DOI
10.1021/ol0059697
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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