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dc.contributor.author金敬順-
dc.creator金敬順-
dc.date.accessioned2016-08-26T10:08:22Z-
dc.date.available2016-08-26T10:08:22Z-
dc.date.issued1979-
dc.identifier.otherOAK-000000032739-
dc.identifier.urihttp://dspace.ewha.ac.kr/handle/2015.oak/200701-
dc.identifier.urihttp://dcollection.ewha.ac.kr/jsp/common/DcLoOrgPer.jsp?sItemId=000000032739-
dc.description.abstractL-2-amino-1-butanol의 光學活性을 變化시키기 위하여 이 化合物을 Co, Raney Ni 및 Co와 Fe₂O₃의 混合觸媒 等 水素添加用 觸媒와 함께 autoclave 속에서 H₂, NH₃ gas 存在下에 200℃에서 反應시킨 結果 Raney Ni과 Co를 각각 觸媒로 使用하였을 경우에 2-amino-1-butanol의 optical rotation이 變化되었으나 結晶性 化合物이 副産沕로 混入되었으며 Co와 Fe₂O₃의 混合比를 99 : 1, 95 : 5, 90 : 10, 80 : 20으로 각각 變化시켜서 反應시킨 結果 모두 2-amino-1-butanol의 optical rotation이 變化되었다. 한편 Co : Fe₂O₃=90 : 10 및 80 : 20으로 각각 混合한 觸媒를 除外하고는 모두 結晶性 化合物인 副産物이 生成되었다.;In order to change the optical rotation of L-2-amino-1-butanol it was treated with hydrogenation catalyst, such as Co, Raney Ni and Co-Fe₂O₃ mixture under the pressure of H₂ and NH₃ gas. The results were as follows : 1. The optical rotation of L-2-amino-1-butanol was changed by Ni, Co and Co-Fe₂O₃ mixed catalyst, respectively. 2. When Ni or Co was used as a catalyst, the crystalline by-product was obtained. 3. We also obtained the crystalline by-product by using the Co-Fe₂O₃ mixed catalyst which contained less than 10% of Fe₂O₃.-
dc.description.tableofcontents論文槪要 = ⅴ Ⅰ. 序論 = 1 Ⅱ. 實驗 = 3 A. 實驗에 使用한 器具 및 試藥 = 3 1. 器具 = 3 2. 試藥 = 3 B. 實驗材料 = 5 C. 實驗方法 = 5 1. 觸媒의 製造 = 5 a. Raney Ni로 부터의 觸媒 製造 = 5 b. Co와 Fe₂O₃ 混合觸媒 = 6 2. Racemization = 6 Ⅲ. 結果 = 8 Ⅳ. 考察 = 16 Ⅴ. 結論 = 18 BIBLIOGRAPHY = 19 ABSTRACT = 21-
dc.formatapplication/pdf-
dc.format.extent502212 bytes-
dc.languagekor-
dc.publisher이화여자대학교 대학원-
dc.subjectα-Aminoalcohol-
dc.subject광학활성-
dc.subject화합물-
dc.titleα-Aminoalcohol의 光學活性 變化에 關한 硏究-
dc.typeMaster's Thesis-
dc.title.translated(The) studies on the change of optical activity of an α-Aminoalcohol-
dc.format.pagev, 21 p.-
dc.identifier.thesisdegreeMaster-
dc.identifier.major대학원 화학과-
dc.date.awarded1980. 2-
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일반대학원 > 화학·나노과학과 > Theses_Master
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